100 Hottest Celebrity Couples of 2010

The romcom queen and her musical husband added a new member to their family this year: a little girl named Naleigh, whom they adopted from South Korea. Heigl is saying goodbye to Grey's Anatomy, but she won't be hurting for work: She has two flicks coming out this year, opposite Josh Duhamel and Ashton Kutcher. Kelley isn't quite as successful as a singer/songwriter, but he's been featured on a few soundtracks to her movies.