Zimbio, in photo: Liv Tyler, boyfriend Joaquin Phoenix
1. Liv Tyler dated Joaquin Phoenix
1995 - 1998

The two meet while shooting on the set of "Inventing the Abbots." They eventually move into together, sharing a home together. Said Pheonix after the end of the relationship, "And at a certain point, I think we stopped evolving with each other, stopped progressing, and made a very mature decision to move on, even though there was still a great love there."