100 Hottest Celebrity Couples of 2010

77. Hilary Duff & Mike Comrie

Duff and her hockey player beau announced they were tying the knot in February after three years of dating. Hilary these days is a far cry from her Disney tween persona, having landed a recurring role on Gossip Girl and been cast in the new Bonnie & Clyde. She also designed a clothing collection with DKNY in 2009. As for Comrie? He signed a $10 million, three-year deal with the Edmonton Oilers, so he's not hurting for cash.